Chem 101 - General Chemistry I » Spring 2021 » Chapter 10 Homework Quiz
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Question #1
A liquid has an enthalpy of vaporization of 31 kJ/mol. At 273 K it has a vapor pressure of 104 mm Hg. What is the normal boiling point of this liquid? (R = 8.3145 J/K· mol)
A.
238.296 K
B.
272.999 K
C.
291.432 K
D.
256.761 K
E.
319.534 K
Question #2
Predict which of the following compounds would have the highest boiling point:
A.
CH3CH2CH2CH3
B.
O2
C.
CH3OCH3
D.
CH3CH2CH2OH
E.
CH3OH
Question #3
Which of the following substances have London Dispersion Forces of attraction? I. He II. CH4 III. H2O
A.
I, II and III
B.
I only
C.
III only
D.
II only
E.
I and II
Question #4
Which of the following processes is endothermic?
A.
freezing of water
B.
condensation of water
C.
melting of ice
D.
deposition of carbon dioxide
E.
condensation of ammonia
Question #5
Which liquid would have the highest viscosity at room temperature?
A.
CH3NH2
B.
C8H17NH2
C.
C9H18
D.
C5H12
E.
C7H14
Question #6
A metal crystallizes in a face-centered cubic lattice. The radius of the atom is 198 pm and the density of the element is 6.5700000000000003 g/cm3. What is the identity of the metal?
A.
Ca
B.
Yb
C.
Sr
D.
Ni
Question #7
At what angle are x-rays with a wavelength of 175 pm diffracted by layers of atoms that are 353 pm apart? (Assume n = 1)
A.
29.7°
B.
none of these
C.
75.6°
D.
14.4°
E.
60.3°
Question #8
Calculate the lattice energy of NaBr(s), given the following thermochemical equations, where IE and EA are ionization energy and electron affinity, respectively. Na(s) → Na(g) ΔH°sublimation = +107 kJ Na(g) → Na+(g) + e– IE = +496 kJ 1/2 Br2(g) → Br(g) ΔHƒ° = +112 kJ Br(g) + e– → Br–(g) EA = –325 kJ Na(s) + 1/2 Br2(g) → NaBr(s) ΔHƒ° = –361 kJ
A.
–290 kJ
B.
+290 kJ
C.
+1403 kJ
D.
–963 kJ
E.
+751 kJ
Question #9
The metal cesium crystallizes in a body-centered cubic lattice. If the density of cesium is 1.88 g/cm3, what is the unit cell volume?
A.
1.77 × 106 pm3
B.
4.70 × 104 pm3
C.
2.35 × 104 pm3
D.
2.35 × 108 pm3
E.
1.17 × 108 pm3
Question #10
According to band theory, an insulator is a material which has a(an) _____ valence band, a(an) _____ conduction band, and a _____ gap between them.
A.
completely filled; completely filled; wide
B.
partially filled; empty; wide
C.
partially filled; partially filled; wide
D.
empty; partially filled; narrow
E.
partially filled; empty; narrow
Question #11
Which equation represents the number of atoms in a primitive cubic unit cell?
A.
# atoms = 1/4 (8)
B.
# atoms = 1/2 (6) + 1/8 (8)
C.
# atoms = 1/8 (8)
D.
# atoms = 1 + 1/2 (6) + 1/8 (8)
E.
# atoms = 1+1/8 (8)
Question #12
An unknown white solid was found to have a melting point of 150oC. It is soluble in water, but it is a poor conductor in aqueous solution. Which of the following substances is the most likely?
A.
Rb
B.
Si
C.
C6H12O6 (glucose)
D.
KCl
E.
C (diamond)
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