Chem 101 - General Chemistry I » Spring 2021 » Chapter 10 Homework Quiz

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Question #1
A liquid has an enthalpy of vaporization of 31 kJ/mol. At 273 K it has a vapor pressure of 104 mm Hg. What is the normal boiling point of this liquid? (R = 8.3145 J/K· mol)
A.   272.999 K
B.   319.534 K
C.   291.432 K
D.   256.761 K
E.   238.296 K
Question #2
Predict which of the following compounds would have the highest boiling point:
A.   CH3OCH3
B.   O2
C.   CH3CH2CH2CH3
D.   CH3CH2CH2OH
E.   CH3OH
Question #3
Which of the following substances have London Dispersion Forces of attraction? I. He II. CH4 III. H2O
A.   III only
B.   I and II
C.   I, II and III
D.   I only
E.   II only
Question #4
Which of the following processes is endothermic?
A.   condensation of water
B.   melting of ice
C.   deposition of carbon dioxide
D.   freezing of water
E.   condensation of ammonia
Question #5
Which liquid would have the highest viscosity at room temperature?
A.   C7H14
B.   C8H17NH2
C.   CH3NH2
D.   C9H18
E.   C5H12
Question #6
A metal crystallizes in a face-centered cubic lattice. The radius of the atom is 198 pm and the density of the element is 6.5700000000000003 g/cm3. What is the identity of the metal?
A.   Ca
B.   Ni
C.   Yb
D.   Sr
Question #7
At what angle are x-rays with a wavelength of 175 pm diffracted by layers of atoms that are 353 pm apart? (Assume n = 1)
A.   75.6°
B.   none of these
C.   29.7°
D.   14.4°
E.   60.3°
Question #8
Calculate the lattice energy of NaBr(s), given the following thermochemical equations, where IE and EA are ionization energy and electron affinity, respectively. Na(s) → Na(g) ΔH°sublimation = +107 kJ Na(g) → Na+(g) + e– IE = +496 kJ 1/2 Br2(g) → Br(g) ΔHƒ° = +112 kJ Br(g) + e– → Br–(g) EA = –325 kJ Na(s) + 1/2 Br2(g) → NaBr(s) ΔHƒ° = –361 kJ
A.   +751 kJ
B.   –290 kJ
C.   –963 kJ
D.   +1403 kJ
E.   +290 kJ
Question #9
The metal cesium crystallizes in a body-centered cubic lattice. If the density of cesium is 1.88 g/cm3, what is the unit cell volume?
A.   1.17 × 108 pm3
B.   4.70 × 104 pm3
C.   1.77 × 106 pm3
D.   2.35 × 108 pm3
E.   2.35 × 104 pm3
Question #10
According to band theory, an insulator is a material which has a(an) _____ valence band, a(an) _____ conduction band, and a _____ gap between them.
A.   empty; partially filled; narrow
B.   partially filled; empty; narrow
C.   partially filled; empty; wide
D.   completely filled; completely filled; wide
E.   partially filled; partially filled; wide
Question #11
Which equation represents the number of atoms in a primitive cubic unit cell?
A.   # atoms = 1/8 (8)
B.   # atoms = 1+1/8 (8)
C.   # atoms = 1 + 1/2 (6) + 1/8 (8)
D.   # atoms = 1/2 (6) + 1/8 (8)
E.   # atoms = 1/4 (8)
Question #12
An unknown white solid was found to have a melting point of 150oC. It is soluble in water, but it is a poor conductor in aqueous solution. Which of the following substances is the most likely?
A.   Rb
B.   C (diamond)
C.   KCl
D.   Si
E.   C6H12O6 (glucose)

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