Chem 221 - Biochemistry for Science Majors » Fall 2021 » L16 Bioenergetics Part 2 of 2
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Question #1
Which of the following is true about oxidation-reduction reactions?
A.
Dehydrogenases typically remove two electrons and two hydrides.
B.
Every oxidation must be accompanied by a reduction.
C.
During oxidation a compound gains electrons.
D.
They usually proceed through homolytic cleavage.
E.
There are four commonly accessed oxidation states of carbon.
Question #2
Biological oxidation-reduction reactions always involve:
A.
mitochondria.
B.
formation of water.
C.
transfer of electron(s).
D.
transfer of hydrogens.
E.
direct participation of oxygen.
Question #3
Which of the following is the ultimate electron acceptor in aerobic organisms?
A.
succinate
B.
oxygen
C.
FAD
D.
NAD+
E.
carbon dioxide
Question #4
What compound serves as an acyl carrier in metabolism?
A.
biotin
B.
tetrahydrofolate
C.
FAD
D.
coenzyme A
E.
thiamine pyrophosphate
Question #5
Which of the following is a 2-electron oxidizing agent used in catabolic pathways?
A.
Riboflavin
B.
NADPH
C.
NAD+
D.
FADH2
E.
None of the answers is correct.
Question #6
Which of the following is a mechanism by which enzyme catalytic activity is controlled?
A.
allosteric control and covalent modification
B.
covalent modification
C.
All the answers are correct.
D.
allosteric control
E.
feedback inhibition
Question #7
The reduced form of flavin adenine dinucleotide is
A.
FADH
B.
FADH2
C.
FADH++
D.
FAD
E.
None of the answers is correct.
Question #8
C3+ is more oxidized than C2-
A.
TRUE
B.
FALSE
Question #9
For the pair of ions below, indicate which is the more highly reduced species. Co2+/Co+
A.
Co2+
B.
Co+
Question #10
For the pair of compounds below, indicate which is the more highly reduced species. Glucose/CO2
A.
Glucose
B.
CO2
Question #11
For the pair of compounds below, indicate which is the more highly reduced species. Acetate/CO2
A.
CO2
B.
Acetate
Question #12
For the pair compounds below, indicate which is the more highly reduced species. Acetic acid/acetaldehyde
A.
Acetic acid
B.
acetaldehyde
Question #13
Electrons are at a lower energy level when they are associated with less electronegative atoms (such as C) and at a higher energy level when they are associated with a more electronegative atom (such as O).
A.
FALSE
B.
TRUE
Question #14
In cellular respiration, electrons from glucose move towards oxygen, passing to lower and lower energy states and releasing energy at each step.
A.
TRUE
B.
FALSE
Question #15
The most reduced form of carbon is CH4, the most oxidized is CO2
A.
TRUE
B.
FALSE
Question #16
C+ is more oxidized than C4-
A.
TRUE
B.
FALSE
Question #17
The most oxidized form of carbon has -4 charge
A.
FALSE
B.
TRUE
Question #18
The more reduced the compound, the richer in oxygen than in hydrogen.
A.
TRUE
B.
FALSE
Question #19
During cellular respiration, the C atoms of glucose increase their oxidation state.
A.
FALSE
B.
TRUE
Question #20
When a molecule accepts electrons it become reduced
A.
TRUE
B.
FALSE
Question #21
Carbon is more electronegative than hydrogen
A.
TRUE
B.
FALSE
Question #22
What is the oxidation state of the carbonyl carbon is acetone?
A.
+1
B.
+2
C.
-2
D.
0
Question #23
What is the oxidation state of C#2 is glycerol?
A.
+2
B.
+1
C.
0
D.
+3
Question #24
The oxidation state of carbon in methane is
A.
+1
B.
+4
C.
-1
D.
-4
Question #25
The oxidation state of carbon in ethene is
A.
+3
B.
+2
C.
-2
D.
-3
Question #26
Ethene is more oxidized than ethane.
A.
FALSE
B.
TRUE
Question #27
Increase in oxidation state means oxidation.
A.
FALSE
B.
TRUE
Question #28
The more oxidized a carbon is to begin with, the more free energy is released upon oxidation.
A.
TRUE
B.
FALSE
Question #29
Oxidized organic compounds serve as fuels from which electrons can be stripped off during oxidation.
A.
FALSE
B.
TRUE
Question #30
Lipids are a more efficient food source than glucose because lipids are more reduced than glucose.
A.
FALSE
B.
TRUE
Question #31
NAD+ and FAD are water-soluble coenzymes
A.
FALSE
B.
TRUE
Question #32
NAD+ and FAD are water-soluble cofactors
A.
FALSE
B.
TRUE
Question #33
NAD+ is usually very tightly bound to the enzymes, for which they serve as prosthetic group.
A.
FALSE
B.
TRUE
Question #34
FAD move readily from one enzyme to another.
A.
TRUE
B.
FALSE
Question #35
NAD+ accepts a hydrogen ion and two electrons, which are equivalent to a hydride ion.
A.
FALSE
B.
TRUE
Question #36
A hydride ion has two protons and two electrons.
A.
TRUE
B.
FALSE
Question #37
A hydride ion has two protons and one electron.
A.
FALSE
B.
TRUE
Question #38
A hydride ion has one proton and one electron.
A.
TRUE
B.
FALSE
Question #39
A hydride ion has one proton and two electrons.
A.
FALSE
B.
TRUE
Question #40
Proteases are hydrolytic enzymes.
A.
FALSE
B.
TRUE
Question #41
Proteases catalyze synthesis reactions
A.
FALSE
B.
TRUE
Question #42
Kinases cleave phosphoryl groups
A.
FALSE
B.
TRUE
Question #43
Dehydrogenations involve the presence of electron carriers.
A.
FALSE
B.
TRUE
Question #44
Isomerization reactions involve an intramolecular rearrangement in which redistribution of electrons result in alterations of my different types without a change in the overall oxidation state of the molecule.
A.
FALSE
B.
TRUE
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