Chem 102 - General Chemistry » Spring 2022 » Exam I

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Question #1
Arrange the given compound and order them according to increasing solubility in Water. (Least soluble to most soluble). (1) CH3CH2CH2CH2CH2CH2CH2OH (2) CH3OCH3 (3) HOCH2CH2OH (4) CCl4
A.   The solubility of CH3CH2CH2CH2CH2CH2CH2OH CCl4 CH3OCH3 HOCH2CH2OH
B.   The solubility of CH3OCH3 CH3CH2CH2CH2CH2CH2CH2OH CCl4 HOCH2CH2OH
C.   The solubility of CCl4 CH3OCH3 CH3CH2CH2CH2CH2CH2CH2OH HOCH2CH2OH
D.   The solubility of CCl4 CH3CH2CH2CH2CH2CH2CH2OH CH3OCH3 HOCH2CH2OH
Question #2
The possible reasons for the solubility of NaCl (solute) in water (H2O) (Solvent) are the ________.
A.   Small amount of energy imputed to break the solute-solute interaction. Small amount of energy released due to mixing of solute and solvent. Small amount of energy imputed to break the solvent-solvent interaction.
B.   Large amount of energy imputed to break the solvent-solvent interaction. Large amount of energy released due to mixing of solute and solvent. Large amount of energy imputed to break the solute-solute interaction.
Question #3
What are the major solute-solvent interactions created when  CH3CH2NH2 dissolves in  CH3CHO?
A.   dipole-dipole
B.   hydrogen bonding
C.   dipole-induced dipole
D.   ion-dipole
E.   ion-induced dipole
F.   London or dispersion
Question #4
Aqueous ammonia is commercially available in a solution that is 31.6% (w/w, w/w means weight/weight) ammonia (Molar Mass of NH3 is 17.03g/mole and water is 18.02g/mole) . What is the molality of ammonia in such a solution? (The density of solution is 1.120 g/mL). (please express your answer to 3 sig figs and just input the value, no units needed) molality = ___ m
A.   27.1 
B.   26.7
C.   23.4
D.   25.2
Question #5
The concentration of iodide in an aqueous solution is 551 parts per million (ppm) by mass. What is the molarity of iodide in sea water? The molar mass of iodide is 126.9g/mole. (The density of sea water is 1.025 g/mL.) (Please express your answer to 2 sig figs and just input the number, no need for units) Molarity of the sea solution is =____ M
A.   0.0039
B.   0.0042 
C.   0.0027
D.   0.0056
Question #6
Two aqueous solutions, A and B, are separated by a semipermeable membrane. The osmotic pressure of solution B immediately begins to decrease. Which of the following statements is true?
A.   (1) Solvent molecules are moving from solution B into solution A.
B.   Both (1) and (3) are true statements.
C.   (2) The initial osmotic pressure of solution B is greater than that of solution A.
D.   (3) The solvent molecules are moving from the solution of higher osmotic pressure to that of lower osmotic pressure.
Question #7
An aqueous solution of CaCl2 has a normal boing point of 108.3 oC. What would be the freezing point of this solution? For water Kb = 0.510 oC/m and Kf = 1.86oC/m. (pure water boils at 100 oC and freezes at 0 oC) (Keep your answer to 3 sig figs and just input the number, no need for units) Tf = ___ oC
A.   -40.6 
B.   -36.8
C.   -30.3 
D.   -28.1 
Question #8
A petroleum company separates benzene (78 g/mol) and n-octane (114 g/mol) by distillation. In one run, the starting solution was 85% n-octane by mass at 25°C. The vapor pressures for benzene and n-octane at this temperature after they are mixed, are 11 torr and 95 torr, respectively. What would be the mole fraction of benzene in the solution?
A.   0.191
B.   0.229
C.   0.205
D.   0.116
Question #9
A petroleum company separates benzene (78 g/mol) and n-octane (114 g/mol) by distillation. In one run, the starting solution was 85% n-octane by mass at 25°C. The vapor pressures for benzene and n-octane at this temperature after they are mixed, are 11 torr and 95 torr, respectively. What would be the mole fraction of benzene in the vapor?
A.   0.104
B.   0.131
C.   0.091
D.   0.214
Question #10
A petroleum company separates benzene (78 g/mol) and n-octane (114 g/mol) by distillation. In one run, the starting solution was 85% n-octane by mass at 25°C. The vapor pressures for benzene and n-octane at this temperature after they are mixed, are 11 torr and 95 torr, respectively. What would be the vapor pressure of pure n-octane?
A.   128 torr
B.   126 torr
C.   119.5 torr
D.   116 torr
Question #11
When a 14.2 g of an unknown compound is dissolved in 200.0 grams of water the boiling point of the solution is 100.56 ˚C. The % ionization of the compound is 39.07 % with an i exp value of 3. (Freezing and boiling point constants for H2O: kf=1.86˚/m, kb= 0.512 ˚/m). What would be the molar mass of the unknown compound = ? g/mol
A.   102
B.   136
C.   116 
D.   129
Question #12
What is the name of the following Transition metal compound, Fe[AlF6]
A.   iron(I) aluminum(III)hexafluoride
B.   iron(III) hexafluoroaluminate(III)
C.   iron(II) hexafluoroaluminum(III)
D.   aluminum hexafluoroferrate
E.   iron aluminum hexafluoride
Question #13
What is the formula of potassium aquabromobis(oxalato)cobaltate(III).
A.   K3[CoBr(H2O)(C2O4)2]
B.   K2[Co(H2O)Br(C2O4)2]
C.   K[Co(H2O)Br(O)2]
D.   K2[Co(H2O)Br(O)2]
E.   none of these
Question #14
The complex ion [V(NH3)4(OH)2]3+ absorbs blue (use 450nm) in aqueous solution. Estimate the crystal field splitting energy (in kJ) for this ion.  ( h = 6.626 x 10-34 J s and c = 3.0 x 108 m/s )     (to enter powers of 10 use the following format:  1.0x10^-8 and keep your answer to 3 sig figs) crystal field splitting energy = ______ kJ
A.   4.42x10^-19
B.   4.36x10^-19
C.   3.99x10^-19
Question #15
The complex ion [V(NH3)4(OH)2]3+ absorbs blue (use 450nm) in aqueous solution. What would be the estimated observed color of the complex ion of [V(NH3)5(OH)]4+ (I- < Br- < Cl- < F- < OH- < H2O < NH3 < en < NO2- < CN- ) The color observed =
A.   white
B.   violet
C.   yellow-orange
Question #16
Please Match the following: Which of the compounds will the possible isomerism? [Cu(SCN)4]3-                  
A.   Optical
B.   No possible isomers
C.   Linkage
D.   Ionization
Question #17
Please Match the following: Which of the compounds will the possible isomerism? [CrC2O4 (OH2)4]-       
A.   Ionization
B.   Cis-Trans
C.   No possible isomers
D.   Fac-Mer
Question #18
Please Match the following: Which of the compounds will the possible isomerism? [Zn(NH3)5Cl]Br  
A.   Ionization
B.   Fac-Mer
C.   Linkage
D.   No possible isomers
Question #19
Please Match the following: Which of the compounds will the possible isomerism? [Cu(CO)5O2]Br        
A.   Optical
B.   Ionization
C.   No possible isomers
D.   Cis-Trans
Question #20
Please Match the following: Which of the compounds will the possible isomerism?  [PtClBr(NH3)N2] (tetrahedral)    
A.   Linkage
B.   Optical
C.   Ionization
D.   Fac-Mer
Question #21
Please Match the following: Which of the compounds will the possible isomerism? [Fe(CO)3(NH3)3]3+       
A.   No possible isomers
B.   Optical
C.   Fac-Mer
D.   Ionization
Question #22
Consider the complex ion [Co(L)6]4- where  L represents a ligand with a charge of -1. The above complex ion has 1 unpaired electron. Select the choices that includes the true statements.
A.   none of the choices are true
B.   The metal ion is a d1 ion. It is diamagnetic.
C.   The ligands are strong field ligands. It is a low spin complex.
D.   The metal ion is a d1 ion. The ligands are strong field ligands.
Question #23
Please indicate if the following molecules are A), paramagnetic or diamagnetic and B), if they exabit color or colorless. [MnF6 ]3-
A.   paramagnetic and colorless
B.   paramagnetic and exabits color
C.   diamagnetic and exabits color
D.   diamagnetic and colorless
Question #24
Please indicate if the following molecules are A), paramagnetic or diamagnetic and B), if they exabit color or colorless. [Co(NH3)6 ]3+
A.   paramagnetic and colorless
B.   diamagnetic and exabits color
C.   diamagnetic and colorless
D.   paramagnetic and exabits color
Question #25
Please indicate if the following molecules are A), paramagnetic or diamagnetic and B), if they exabit color or colorless. [Fe(NO2)6 ]3-
A.   diamagnetic and colorless
B.   paramagnetic and exabits color
C.   paramagnetic and colorless
D.   diamagnetic and exabits color
Question #26
Please indicate if the following molecules are A), paramagnetic or diamagnetic and B), if they exabit color or colorless. [Fe(NH3)4 ]3+
A.   diamagnetic and exabits color
B.   diamagnetic and colorless
C.   paramagnetic and colorless
D.   paramagnetic and exabits color
Question #27
Consider the following reaction 8A(g) + 5B(g) → 8C(g) + 6D(g) If [C] is increasing at the rate of 4.0 M/s, at what rate is [B] changing?
A.   4.8 M/s
B.   0.40 M/s
C.   None is correct
D.   2.5 M/s
E.   3.3 M/s
F.   6.4 M/s

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